| List-I (Equilibrium Process) |
List-II (Physical Properties) |
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| A. | \(Liquid \rightleftharpoons Vapour\) | I. | Melting point |
| B. | \(Solid \rightleftharpoons Liquid\) | II. | Boiling point |
| C. | \(Solid \rightleftharpoons Vapour\) | III. | Sublimation point |
| D. | \(\small {Solute (solid) \rightleftharpoons Solute (solution)}\) | IV. | Saturated solution |
| V. | Unsaturated solution |
Consider the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene. The correct statement is:
Assume that the temperature is constant at 25 oC.
(Given, vapour pressure data at 25 °C, benzene = 12.8 kPa, toluene = 3.85 kPa)
| 1. | The vapour will contain a higher percentage of toluene. |
| 2. | The vapour will contain equal amounts of benzene and toluene. |
| 3. | Not enough information is given to make a prediction. |
| 4. | The vapour will contain a higher percentage of benzene. |
The electrolyte having the same value of Van't Hoff factor (i) as that of Al2(SO4)3 (if all are 100% ionized) is:
| 1. | K2SO4 | 2. | K3[Fe(CN)6] |
| 3. | Al(NO3)3 | 4. | K4[Fe(CN)6] |
| 1. | B > C > A | 2. | A > C > B |
| 3. | A > B > C | 4. | B > A > C |
| Assertion (A): | Helium is used to dilute oxygen in the diving apparatus. |
| Reason (R): | Helium has a high solubility in O2. |
| 1. | (A) is False but (R) is True. |
| 2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 3. | Both (A) and (R) are True and (R) is not the correct explanation of (A). |
| 4. | (A) is True but (R) is False. |
| gas | KH/k bar |
| Ar | 40.3 |
| CO2 | 1.67 |
| HCHO | 1.83 × 10–5 |
| CH4 | 0.413 |
| 1. | Ar < CO2 < CH4 < HCHO |
| 2. | Ar < CH4 < CO2 < HCHO |
| 3. | HCHO < CO2 < CH4 < Ar |
| 4. | HCHO < CH4 < CO2 < Ar |
| 1. | 1000 g of solvent | 2. | 500 mL of solvent |
| 3. | 500 g of solvent | 4. | 100 mL of solvent |
pA and pB are the vapour pressure of pure liquid components, A and B, respectively of an ideal binary solution.
If XA represents the mole fraction of component A, the total pressure of the solution will be:
| 1. | pA + XA (pB-pA) | 2. | pA + XA (pA-pB) |
| 3. | pB + XA (pB-pA) | 4. | pB + XA (pA-pB) |
The correct option for the value of vapour pressure of a solution at 45 C with benzene to octane in a molar ratio 3:2 is:
[At 45 C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]
| 1. | 336 mm of Hg | 2. | 350 mm of Hg |
| 3. | 160 mm of Hg | 4. | 168 mm of Hg |